Experimental and Modeling Study of the Oxidation of 1-Butene and cis-2-Butene in a Jet-Stirred Reactor and a Combustion Vessel

Experimental and Modeling Study of the Oxidation of 1-Butene and cis-2-Butene in a Jet-Stirred Reactor and a Combustion Vessel
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DOI:
10.1021/ef502732c
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发表时间:
2015-02-01
期刊:
影响因子:
5.3
通讯作者:
Dagaut, Philippe
Dagaut, Philippe
中科院分区:
工程技术3区
文献类型:
--
作者:
Fenard, Yann;Dayma, Guillaume;Dagaut, Philippe

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大量的不饱和烃,如丁烯异构体,在高级烃的氧化过程中作为中间产物形成。在本研究中,获得了新的实验数据,1-丁烯和顺-2-丁烯的氧化。实验在喷射搅拌反应器中进行,温度范围为900 ~ 440 K,常压,不同当量比(0.25
Significant amounts of unsaturated hydrocarbons, such as butene isomers, are formed as intermediate products during the oxidation of higher hydrocarbons. In this study, new experimental data were obtained for the oxidation of 1-butene and cis-2-butene. The experiments were conducted in a jet-stirred reactor in the temperature range of 9001440 K, at atmospheric pressure, for different equivalence ratios (0.25