Tertiary phosphines and P-chiral phosphinites bearing a fullerene substituent
Tertiary phosphines and P-chiral phosphinites bearing a fullerene substituent
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带有富勒烯取代基的叔膦和P-手性次膦酸酯
DOI：
10.1039/c39940002093
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发表时间：
1994
期刊：
影响因子：
--
通讯作者：
E. Nakamura
中科院分区：
文献类型：
--
作者：
S. Yamago;M. Yanagawa;E. Nakamura
锂化膦-硼烷或次膦酸酯硼烷与C60的反应，随后除去BH 3基团，得到具有富勒烯取代基的膦或次膦酸酯，其在磷原子上以1：1和2：1化学计量选择性地与BH 3和PtCl 2络合。
The reaction of a lithiated phosphine–borane or a phosphinite borane with C60 followed by removal of the BH3 group affords a phosphine or a phosphinite bearing a fullerene substituent, which undergoes complexation with BH3 and PtCl2 selectively on the phosphorus atom with 1 : 1 and 2 : 1 stoichiometry.