A simple helix based on 2,2′-biimidazole. Crystal and molecular structure of [Ag(NO3)(H2biim)]n
A simple helix based on 2,2′-biimidazole. Crystal and molecular structure of [Ag(NO3)(H2biim)]n
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基于 2,2-联咪唑的简单螺旋 [Ag(NO3)(H2biim)]n 晶体和分子结构。
DOI：
10.1016/s0277-5387(97)00022-3
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发表时间：
1997
期刊：
影响因子：
--
通讯作者：
H. Collier
中科院分区：
文献类型：
--
作者：
C. Hester;R. G. Baughman;H. Collier
银（I）硝酸盐和2，2 ′-联咪唑（H2 biim）从水溶液中结晶，得到单链螺旋，如X射线晶体学所证明。该组装是基于H2 biim的近似顺式构象，其与配位的银（I）原子的优选线性双配位性质一致。
Silver(I) nitrate and 2,2′-biimidazole (H2biim) crystallize from an aqueous solution to afford a single-strand helix, as evidenced by X-ray crystallography. This assemblage is based on an approximate cis conformation of H2biim acting in concert with the preferred linear two-coordinate nature of the ligated silver(I) atom.