Smiles rearrangement for the synthesis of diarylamines
Smiles rearrangement for the synthesis of diarylamines
复制标题
Smiles重排合成二芳基胺
DOI：
10.3998/ark.5550190.0012.a10
复制
发表时间：
2011-08
期刊：
影响因子：
0.9
通讯作者：
Zuo, Hua
中科院分区：
文献类型：
--
作者：
Tian, Xiao;Wu, Ren-Min;Liu, Gang;Li, Zhu-Bo;Wei, He-Lin;Yang, Hao;Shin, Dong-Soo;Wang, Li-Ying;Zuo, Hua
已经开发出一种在微波辐射下通过 Smiles 重排一锅合成二芳基胺的方案。从容易获得的取代苯酚、芳胺和氯乙酰氯出发，可以有效地合成各种二芳基胺，产率中等至良好（58-92%）。
A protocol for the one-pot synthesis of diarylamines via Smiles rearrangement under microwave irradiation has been developed. Various diarylamines were effectively synthesized starting from readily available substituted phenols, arylamines and chloroacetyl chloride in moderate to good yields (58–92%).