Anisotropic water chain growth on Cu(110) observed with scanning tunneling microscopy.

Anisotropic water chain growth on Cu(110) observed with scanning tunneling microscopy.
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DOI:
10.1103/physrevlett.96.036105
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发表时间:
2006-01
影响因子:
8.6
通讯作者:
Takashi Yamada;S. Tamamori;H. Okuyama;T. Aruga
Takashi Yamada;S. Tamamori;H. Okuyama;T. Aruga
中科院分区:
物理与天体物理1区
文献类型:
--
作者:
Takashi Yamada;S. Tamamori;H. Okuyama;T. Aruga

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我们用扫描隧道显微镜报道了一种新的水聚集体结构。水分子在78K下在Cu(110)表面自组装成一维链状结构。该链呈现锯齿形结构,周期为7.2A,并增长到约1000A的长度。我们提出水六聚体沿链沿着交替排列。由于偶极相互作用而产生的链间排斥促进了一维链的生长。二维覆盖层仅在高覆盖率下形成。
We report a novel structure of water aggregate by means of scanning tunneling microscopy. Water molecules are self-assembled into one-dimensional chains on Cu(110) at 78 K. The chain exhibits a zigzag structure with a period of 7.2 A and grows to a length of approximately 1000 A. We propose that water hexamers are arranged alternately along the chain. Interchain repulsion due to dipole interaction facilitates the 1D chain growth. A two-dimensional overlayer develops only at high coverage.