A novel mixed-valence complex containing Co(II)(2)Co(III)(2) molecular squares with 4,5-imidazoledicarboxylate bridges.
A novel mixed-valence complex containing Co(II)(2)Co(III)(2) molecular squares with 4,5-imidazoledicarboxylate bridges.
复制标题
DOI：
10.1039/b315357f
复制
发表时间：
2004-03
影响因子：
4.9
通讯作者：
Chuanfeng Wang;E. Gao;Zheng He;Chunhua Yan
中科院分区：
文献类型：
--
作者：
Chuanfeng Wang;E. Gao;Zheng He;Chunhua Yan
水热合成了一种异金属配合物Na（2）[Co（II）（2）Co（III）（2）（IDC（3-））（4）（bipy）（4）]. 12 H（2）O（bipy = 2，2 '-bipyridine），其中混合价四核正方形与咪唑二羧酸（IDC（3-））连接体通过二钠单元连接成独特的链，并对其结构和磁性进行了表征。
A heterometallic complex, Na(2)[Co(II)(2)Co(III)(2)(IDC(3-))(4)(bipy)(4)].12H(2)O (bipy = 2,2'-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC(3-)) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.