Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage.
Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage.
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DOI：
10.1021/acs.orglett.6b01250
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发表时间：
2016-05
期刊：
影响因子：
5.2
通讯作者：
Y. Uetake;Takashi Niwa;T. Hosoya
中科院分区：
文献类型：
--
作者：
Y. Uetake;Takashi Niwa;T. Hosoya
报道了铑催化C-S键裂解烷基芳基硫化物转化为芳基硼酸蒎醇酯。结合过渡金属催化的磺胺基引导的烷基硫代芳烃的区域选择性C-H硼化反应，该方法可以合成多种多取代芳烃。
Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C-S bond cleavage is reported. In combination with transition-metal-catalyzed sulfanyl group-guided regioselective C-H borylation reactions of alkylthioarenes, this method allows the synthesis of a diverse range of multisubstituted arenes.