Dual modification of a triple-stranded β-helix nanotube with Ru and Re metal complexes to promote photocatalytic reduction of CO2.
Dual modification of a triple-stranded β-helix nanotube with Ru and Re metal complexes to promote photocatalytic reduction of CO2.
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DOI：
10.1039/c0cc03015e
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发表时间：
2011-02
影响因子：
4.9
通讯作者：
Norihiko Yokoi;Y. Miura;Chen-Yuang Huang;Nobuyuki Takatani;H. Inaba;T. Koshiyama;S. Kanamaru;F. Arisaka;Y. Watanabe;S. Kitagawa;T. Ueno
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文献类型：
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作者：
Norihiko Yokoi;Y. Miura;Chen-Yuang Huang;Nobuyuki Takatani;H. Inaba;T. Koshiyama;S. Kanamaru;F. Arisaka;Y. Watanabe;S. Kitagawa;T. Ueno
我们从噬菌体T4的组分蛋白质中构建了一个坚固的β-螺旋纳米管，并用Ru（II）（bpy）（3）和Re（I）（bpy）（CO）（3）Cl配合物修饰了该纳米管。布置在管上的光催化系统以比单体形式的混合物更高的反应性催化CO（2）的还原。
We have constructed a robust β-helical nanotube from the component proteins of bacteriophage T4 and modified this nanotube with Ru(II)(bpy)(3) and Re(I)(bpy)(CO)(3)Cl complexes. The photocatalytic system arranged on the tube catalyzes the reduction of CO(2) with higher reactivity than that of the mixture of the monomeric forms.