New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage.

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage.
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DOI:
10.1039/b209445b
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发表时间:
2002-12
影响因子:
4.9
通讯作者:
L. Jones;E. Brechin;D. Collison;A. Harrison;S. Teat;W. Wernsdorfer
L. Jones;E. Brechin;D. Collison;A. Harrison;S. Teat;W. Wernsdorfer
中科院分区:
化学2区
文献类型:
--
作者:
L. Jones;E. Brechin;D. Collison;A. Harrison;S. Teat;W. Wernsdorfer

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MnF3与苯并三氮唑(BTAH)在热甲醇中反应生成Mn(III)配合物[Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)],该配合物在低温下表现出磁滞现象和与温度无关的磁化弛豫。
The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.