Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide
Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide
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DOI：
10.1246/cl.2006.820
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发表时间：
2006-06
影响因子：
1.6
通讯作者：
K. Nemoto;Hiroki Yoshida;Yutaka Suzuki;Naoya Morohashi;T. Hattori
中科院分区：
文献类型：
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作者：
K. Nemoto;Hiroki Yoshida;Yutaka Suzuki;Naoya Morohashi;T. Hattori
通过添加大量过量的三甲基氯硅烷(TMSCl)，可以显着促进芳香族化合物与CO 2 的路易斯酸介导的羧化反应，从而以良好至优异的收率得到芳基羧酸。
The Lewis acid-mediated carboxylation of aromatic compounds with CO 2 is significantly promoted by the addition of a large excess of chlorotrimethylsilane (TMSCl) to give arylcarboxylic acids in good to excellent yields.