A tris(mu-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue.
A tris(mu-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue.
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作为漆酶天然中间体模型的三（μ-羟基）三铜（II）复合物及其与双核类似物的关系。
DOI：
10.1021/ic048182b
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发表时间：
2005
期刊：
影响因子：
--
通讯作者：
Stack,TDanielP
中科院分区：
文献类型：
--
作者：
Mirica,LiviuM;Stack,TDanielP
铜(I)络合物与空间要求很高的仲二胺配体和O2反应生成三(μ-羟基)三铜(II)络合物。该络合物是多铜氧化酶天然中间体的结构模型，具有有趣的结构、磁性和溶液性质。
The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2yields a tris(μ-hydroxy)tricopper(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.