Hydrogen bond structural group constants
Hydrogen bond structural group constants
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DOI：
10.1021/jo001765s
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发表时间：
2001-05-18
影响因子：
3.6
通讯作者：
Platts, JA
中科院分区：
文献类型：
--
作者：
Abraham, MH;Platts, JA
官能团作为氢键酸和碱的能力可以从1：1氢键的平衡常数或总氢键常数获得。这两种方法都导致氢键的结构常数在某种程度上类似于取代基常数。这些功能基团常数的广泛列表的报告。结果表明，由总氢键常数导出的结果更适用于理化和生化性质的分析。
The ability of functional groups to act as hydrogen bond acids and bases can be obtained from either equilibrium constants for 1:1 hydrogen bonding or overall hydrogen bond constants. Either method leads to structural constants for hydrogen bonding that in some way are analogous to substituent constants. Extensive lists of these functional group constants are reported. It is shown that those derived from overall hydrogen bond constants are the more useful in analyses of physicochemical and biochemical properties.