Circularly Polarized Luminescence from Simple Organic Molecules.

Circularly Polarized Luminescence from Simple Organic Molecules.
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DOI:
10.1002/chem.201501178
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发表时间:
2015-09-21
期刊:
Chemistry (Weinheim an der Bergstrasse, Germany)
影响因子:
--
通讯作者:
de la Moya S
de la Moya S
中科院分区:
其他
文献类型:
--
作者:
Sánchez-Carnerero EM;Agarrabeitia AR;Moreno F;Maroto BL;Muller G;Ortiz MJ;de la Moya S

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本文旨在展示“CPL活性的简单有机分子”作为有机化学中的一个新概念的同一性,这是由于与它们相关的研究文章的指数增长所带来的潜在的兴趣。特别是,它描述和强调了开发能够有效地发射左或右圆偏振光的手性简单(小的和非聚集的)有机分子的兴趣和困难,到目前为止为实现这一具有挑战性的目标所做的努力,以及迄今所取得的最重要的里程碑。还介绍了制备这些感兴趣的分子的一般指导方针。
This article aims to show the identity of “CPL-active simple organic molecules” as a new concept in Organic Chemistry due to the potential interest of these molecules, as availed by the exponentially growing number of research articles related to them. In particular, it describes and highlights the interest and difficulty in developing chiral simple (small and nonaggregated) organic molecules able to emit left- or right-circularly polarized light efficiently, the efforts realized up to now to reach this challenging objective, and the most significant milestones achieved to date. General guidelines for the preparation of these interesting molecules are also presented.