Preparation of methyl chalcogenated derivatives of 1,4,5,8-tetrathiatetralin
Preparation of methyl chalcogenated derivatives of 1,4,5,8-tetrathiatetralin
复制标题
1,4,5,8-四硫四氢化萘甲基硫属化衍生物的制备
DOI：
10.1039/c39940000841
复制
发表时间：
1994
期刊：
影响因子：
--
通讯作者：
H. Anzai
中科院分区：
文献类型：
--
作者：
S. Nakatsuji;Yoshiki Amano;H. Kawamura;H. Anzai
四硫代四氢化萘（TTT）2与二异丙基氨基锂和MeSSMe或MeSeSeMe在乙醚中反应，成功地合成了四（甲硫基）-1，4，5，8-四硫代四氢化萘4和四（甲硒基）-1，4，5，8-四硫代四氢化萘6，并在四氢呋喃中通过一种新的重排反应，观察到了明显的溶剂效应，得到了四（甲硫基）四硫富瓦烯5.
Tetrakis(methylthio)-1,4,5,8-tetrathiatetralin 4 and tetrakis (methylseleno)-1,4,5,8-tetrathiatetralin 6 is successfully prepared by the reaction of tetrathiatetralin (TTT)2 with lithium diisopropylamide and MeSSMe or MeSeSeMe in diethyl ether and a remarkable solvent effect is observed in the analogous reaction in tetrahydrofuran to give tetrakis(methylthio)tetrathiafulvalene 5 by a novel rearrangement.