How to stop a molecular rotator. Mössbauer spectroscopic studies on (η-benzene)(η-cyclopentadienyl)iron(II) hexafluorophosphate in the presence and absence of high pressure

How to stop a molecular rotator. Mössbauer spectroscopic studies on (η-benzene)(η-cyclopentadienyl)iron(II) hexafluorophosphate in the presence and absence of high pressure
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如何在存在和不存在高压的情况下停止分子旋转器。

DOI:
10.1039/cc9960000011
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发表时间:
1996
期刊:
影响因子:
--
通讯作者:
C. McCammon
C. McCammon
中科院分区:
--
文献类型:
--
作者:
J. Silver;R. Roberts;D. Davies;C. McCammon

文献摘要

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在室温下施加1.79 GPa的压力对(η-苯)(η-苯)六氟磷酸铁(II)的应用显示出抑制阳离子的动态重取向;使用穆斯堡尔谱研究了压力的影响。
Application of a pressure of 1.79 GPa, at room temperature on (η-benzene)(η-cyclopentadienyl)iron(II) hexafluorophosphate is shown to arrest the dynamic reorientation of the cations; the effect of pressure is studied using Mossbauer spectroscopy.