Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
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DOI：
10.1039/c1cc11823d
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发表时间：
2011-05
影响因子：
4.9
通讯作者：
R. Shintani;Rintaro Narui;Yosuke Tsutsumi;S. Hayashi;Tamio Hayashi
中科院分区：
文献类型：
--
作者：
R. Shintani;Rintaro Narui;Yosuke Tsutsumi;S. Hayashi;Tamio Hayashi
Novel chiral phosphorus-olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity.
