Synthesis of a kairomone and other chemicals from cardanol, a renewable resource
Synthesis of a kairomone and other chemicals from cardanol, a renewable resource
复制标题
从可再生资源腰果酚合成利他酮和其他化学品
DOI：
--
复制
发表时间：
2012
期刊：
影响因子：
--
通讯作者：
D. Cole
中科院分区：
文献类型：
--
作者：
Juma A. Mmongoyo;Q. Mgani;S. Mdachi;P. Pogorzelec;D. Cole
使用腰果酚[3-（十五碳-8-烯基）苯酚]合成了采采蝇利它素组分（3-丙基苯酚）、洗涤剂[2-（癸-8-烯基）-6-羟基苯磺酸钠]、聚合物添加剂（1-辛烯）和洗涤剂前体[3-（壬-8-烯基）苯酚]。碳-碳双键异构化和复分解两种方法被用于合成这些目标分子。利它素组分是从腰果酚开始分三步得到的，尽管产率很低。以腰果酚为原料，经顺式-2-丁烯直接复分解、磺化、碱化，合成了新型洗涤剂2-（癸-8-烯基）-6-羟基苯磺酸钠。最后，以腰果酚和乙烯为原料，一锅法合成了1-辛烯和3-壬-8-烯基苯酚。这些产物已经通过光谱，特别是使用1H和13 C NMR进行了表征。
Synthesis of a tsetse fly kairomone component (3-propylphenol), a detergent [sodium 2-(dec-8-enyl)-6-hydroxybenzenesulfonate], a polymer additive (1-octene), and a detergent precursor [3-(non-8-enyl)phenol] using cardanol [3-(pentadec-8-enyl)phenol], has been accomplished. Both carbon–carbon double bond isomerization and metathesis methodologies were employed in the syntheses of these target molecules. The kairomone component was obtained, albeit in low yield, in three steps starting with cardanol. Synthesis of a new detergent, sodium 2-(dec-8-enyl)-6-hydroxybenzenesulfonate, was achieved by direct metathesis of cardanol with cis-2-butene followed by sulfonation and basification. Finally, synthesis of 1-octene and 3-(non-8-enyl)phenol was accomplished in one pot by direct metathesis of cardanol with ethylene. These products have been characterized spectroscopically, especially using 1H and 13C NMR.
影响因子：
5.2
作者：
Ahn, YM;Yang, K;Georg, GI
通讯作者：
Georg, GI