Migration of di(2-ethylhexyl)phthalate (DEHP) and di-n-butylphthalate (DBP) from polypropylene food containers
Migration of di(2-ethylhexyl)phthalate (DEHP) and di-n-butylphthalate (DBP) from polypropylene food containers
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DOI：
10.1016/j.foodcont.2016.10.050
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发表时间：
2017-03-01
期刊：
影响因子：
6
通讯作者：
Lynch, Robert A.
中科院分区：
文献类型：
--
作者：
Fang, Haiqin;Wang, Jun;Lynch, Robert A.
邻苯二甲酸二（2-乙基己基）酯（DEHP）和邻苯二甲酸二正丁酯（DBP）暴露于食品包装材料迁移会对生殖、发育、免疫和内分泌系统产生不利影响。的. DEHP和DBP从聚氯乙烯塑料食品容器中迁移是有据可查的。然而，被认为是“绿色”的聚丙烯塑料食品容器却没有被检查过。本初步研究的目的是确定市售聚丙烯食品容器中邻苯二甲酸酯迁移到食品类水溶液中的水平。在4种不同pH值（3、5、7、9）下从聚丙烯容器中取出液体样品，类似于酸性至碱性条件，加热时间为0-5 min。结果表明，DEHP和DBP在强酸性（pH=3）下迁移最多，最高累积浓度分别为159.8和104.9 μ g/L。迁移也随着加热时间的延长而增加。聚丙烯食品容器中DBP的最高迁移量（0.6 mg/kg）超过特定迁移限度。(C)2016爱思唯尔有限公司版权所有
Di(2-ethylhexyl)phthalate (DEHP) and di-n-butylphthalate (DBP) exposure from food packaging material migration can adversely affect the reproductive, developmental, immune, and endocrine systems. The. migration of DEHP and DBP from polyvinyl chloride plastic food containers was well documented. However, supposedly "green" polypropylene plastic food containers have not been examined. The objective of this preliminary study was to determine the level of phthalate migration from commercially available polypropylene food containers into food-alike aqueous solutions. The liquid samples were retrieved from polypropylene containers under four different pH values (3, 5, 7, 9) resembling acidic to basic conditions, with a heating time of 0-5 min. The results showed that both DEHP and DBP had the highest migration under strong acidity (pH=3), with the highest cumulative concentrations of 159.8 and 104.9 mu g/L, respectively. Migration also increased with prolonged heating time. The highest migration of DBP from the polypropylene food container (0.6 mg/kg) exceeded specific migration limit. (C) 2016 Elsevier Ltd. All rights reserved.