ZnO as a new catalyst for N-formylation of amines under solvent-free conditions
ZnO as a new catalyst for N-formylation of amines under solvent-free conditions
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DOI：
10.1021/jo060847z
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发表时间：
2006-08-18
影响因子：
3.6
通讯作者：
Sharghi, Hashem
中科院分区：
文献类型：
--
作者：
Hosseini-Sarvari, Mona;Sharghi, Hashem
在无溶剂条件下，在ZnO存在下用甲酸处理胺，可实现高效的n -甲酰化反应，得到相应的甲酰胺，产率高。n -甲酰化反应具有条件温和、操作简单、产率高、化学选择性高等优点。
The treatment of amines with formic acid in the presence of ZnO under solvent-free conditions brings about highly and efficient N-formylation to give the corresponding formamides in excellent yields. The N-formylation reaction not only involves mild conditions, simple operation, and high yields but also high chemoselectivity.