Marsdenosides A-H, polyoxypregnane glycosides from Marsdenia tenacissima

Marsdenosides A-H, polyoxypregnane glycosides from Marsdenia tenacissima
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DOI:
10.1016/j.phytochem.2005.03.018
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发表时间:
2005-05-01
期刊:
影响因子:
3.8
通讯作者:
Chen, DF
Chen, DF
中科院分区:
生物学2区
文献类型:
--
作者:
Deng, J;Liao, ZX;Chen, DF

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从 Marsdenia tenacissima 茎乙醇提取物的 CHCl3 可溶部分中分离出八种聚氧孕烷糖苷(marsdenasides A-H),以及六种已知的糖苷和两种已知的聚氧孕烷苷元。还获得了三种聚氧孕烷、12β-O-2-甲基丁酰基-腱生菌素A、11α,12β-二-O-乙酰腱生菌素B和11α-O-虎杖酰基腱菌素B。它们的结构是在光谱分析和化学证据的基础上建立的。 (c) 2005 Elsevier Ltd. 保留所有权利。
Eight polyoxypregnane glycosides, marsdenosides A-H, were isolated from the CHCl3-soluble fraction of the ethanolic extract of the stem of Marsdenia tenacissima, along with six known glycosides and two known polyoxypregnane aglycones. Three polyoxy-pregnanes, 12 beta-O-2-methylbutyryl-tenacigenin A, 11 alpha,12 beta-di-O-acetyltenacigenin B, and 11 alpha-O-tigloyltenacigenin B were also obtained. Their structures were established on the basis of spectroscopic analysis and chemical evidence. (c) 2005 Elsevier Ltd. All rights reserved.