Palladium(IV) in an Oxoanionic Environment: The XeF2 Assisted Synthesis of [Pd(S2 O7 )3 ](2.).
Palladium(IV) in an Oxoanionic Environment: The XeF2 Assisted Synthesis of [Pd(S2 O7 )3 ](2.).
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DOI：
10.1002/anie.201601767
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发表时间：
2016-07
影响因子：
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通讯作者：
Jörn Bruns;David van Gerven;T. Klüner;M. Wickleder
中科院分区：
文献类型：
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作者：
Jörn Bruns;David van Gerven;T. Klüner;M. Wickleder
第一次检测到四价钯，仅由简单的含氧阴离子协调。通过形成[Pd（S2 O 7）3 ]（2-）络合物实现稳定化，其中三个螯合二硫酸根基团围绕金属原子。K2 [Pd（S2 O 7）3 ]盐只有在XeF 2存在下与纯SO 3反应才能得到。
For the first time tetravalent palladium is detected, coordinated exclusively by simple oxoanions. Stabilization was achieved by formation of the [Pd(S2 O7 )3 ](2-) complex in which three chelating disulfate groups surround the metal atom. The salt K2 [Pd(S2 O7 )3 ] could only be obtained if the reaction of K2 [PdCl6 ] and neat SO3 was performed in the presence of XeF2 .