Metallo‐Supramolecular Assemblies Incorporating 1,3‐ and 1,4‐Aryl Linked Bis‐β‐diketones — Some Recent Studies
Metallo‐Supramolecular Assemblies Incorporating 1,3‐ and 1,4‐Aryl Linked Bis‐β‐diketones — Some Recent Studies
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包含 1,3- 和 1,4-芳基连接的双-β-二酮的金属超分子组装体 - 一些最新研究
DOI：
10.1002/chin.200832221
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发表时间：
2008
期刊：
影响因子：
--
通讯作者：
G. Meehan
中科院分区：
文献类型：
--
作者：
J. Clegg;K. Jolliffe;L. Lindoy;G. Meehan
综述了1，3-和1，4-芳基连接的双-β-二酮类化合物与二价和三价金属离子相互作用的研究进展。在某些情况下，双官能团桥联配体被用来将所得到的结构从二维延伸到三维。文中还讨论了金属超分子双核‘平台’、四核界面二聚体、双核螺旋、三核三角形、阶梯状金属聚合物、柱状聚合物和含大空腔的四核四面体的例子。
A review of recent work in the authors' laboratories involving the interaction of 1,3- and 1,4-aryl linked bis-β-diketone derivatives with divalent and trivalent metal ions is presented. In some instances, bifunctional bridging ligands have been employed to extend the resulting structures from two to three dimensions. Examples of metallo-supramolecular dinuclear 'platforms', tetranuclear cofacial dimers, dinuclear helicates, trinuclear triangles, stepped metallo-polymers, a prismatic columnar polymer and large cavity-containing, tetranuclear tetrahedra are all discussed.