Outer-sphere coordination of organic molecules to electrically neutral metal complexes
Outer-sphere coordination of organic molecules to electrically neutral metal complexes
复制标题
有机分子与电中性金属配合物的外层配位
DOI：
10.1016/0010-8545(85)80005-9
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发表时间：
1983
影响因子：
0.8
通讯作者：
K. Zamaraev
中科院分区：
文献类型：
--
作者：
V. M. Nekipelov;K. Zamaraev
传统的对溶液中金属配合物的物理化学性质的描述是基于一个模型，该模型考虑了两种类型的相互作用：(i)金属原子（离子）与第一（内）配位球的配体之间的特定化学相互作用，以及（ii）内球金属配合物与介质作为介电连续体的非特异性相互作用。对于带电金属配合物和电中性金属配合物，这两种相互作用的相对作用有很大的不同。在前一种情况下，金属配合物的相互作用能
The traditional description of the physico-chemical properties of metal complexes in solutions is based on a model which takes into account interactions of two types:(i) specific chemical interaction between the metal atom (ion) and the ligands of the first (inner) coordination sphere, and (ii) non-specific interaction of the inner-sphere metal complex with the medium as a dielectric continuum. The relative role of these two interactions differs substantially for electrically charged and electrically neutral metal complexes. In the former case the energy of interaction of the metal complex