Cytochrome c Cross-linked with Glutaraldehyde (1); Electrochemical Response in Poly(ethylene oxide) Oligomers.

Cytochrome c Cross-linked with Glutaraldehyde (1); Electrochemical Response in Poly(ethylene oxide) Oligomers.
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细胞色素 c 与戊二醛交联 (1);

DOI:
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发表时间:
1996
期刊:
影响因子:
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通讯作者:
F. Kurusu
F. Kurusu
中科院分区:
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文献类型:
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作者:
H. Ohno;F. Kurusu

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为了在聚环氧乙烷(PEO)齐聚物中实现细胞色素c(cyt.c)的快速电子转移,将细胞色素c的高有序结构与戊二醛进行分子内交联,并对其氧化还原反应进行了分析。交联型细胞色素c可溶于PEO齐聚物,表现出比PEO修饰的细胞色素c更好的电化学氧化还原响应。即使在电极上吸附后,交联型细胞色素c的构象也几乎没有变化。
For rapid electron transfer of cytochrome c(cyt.c) in poly(ethylene oxide)(PEO) oligomers, higher-ordered structure of cyt.c was cross-linked intramolecularly with glutaraldehyde, and the redox reaction of this cyt.c was analyzed. The cross-linked cyt.c was soluble in PEO oligomers and showed better electrochemical redox response than PEO-modified cyt.c. Little conformational change of the cross-linked cyt.c was suggested even after adsorption on the electrode.
DOI: 10.1021/bc00027a008
发表时间: 1994-05-01
影响因子: 4.7
作者:
MABROUK, PA
通讯作者: MABROUK, PA