Solid-state and solution structure of a hypervalent AX5 compound: Sb(C6F5)5.
Solid-state and solution structure of a hypervalent AX5 compound: Sb(C6F5)5.
复制标题
高价 AX5 化合物的固态和溶液结构：Sb(C6F5)5。
作者：
M. A. García;P. Alonso;I. Ara;B. Menjón;P. Romero
消除限制：三角-双锥体结构已被发现是高价AX(5)分子Sb(C(6)F(5))(5)在固态和流体溶液中的能量有利的几何结构，其中分子自由移动并且没有晶体堆积效应。
Eliminating restraints: a trigonal-bipyramidal structure has been found to be the energetically favored geometry of the hypervalent AX(5) molecule Sb(C(6)F(5))(5) in the solid state and also in fluid solution, where molecules move freely and no crystal packing effects operate.