Enecarbamates as imine surrogates: nucleophilic addition of 1,3-dicarbonyl compounds to enecarbamates.
Enecarbamates as imine surrogates: nucleophilic addition of 1,3-dicarbonyl compounds to enecarbamates.
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DOI：
10.1002/chin.200710034
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发表时间：
2006-09
期刊：
影响因子：
5.2
通讯作者：
S. Kobayashi;T. Gustafsson;Y. Shimizu;H. Kiyohara;R. Matsubara
中科院分区：
文献类型：
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作者：
S. Kobayashi;T. Gustafsson;Y. Shimizu;H. Kiyohara;R. Matsubara
[反应：见正文] 1，3-二羰基化合物与烯氨基甲酸酯的新型曼尼希型反应已经被开发出来。稳定且可储存的烯氨基甲酸酯用作脂肪族糖苷衍生的亚胺的替代物，已知脂肪族糖苷衍生的亚胺难以分离和储存。
[reaction: see text] Novel Mannich-type reactions of 1,3-dicarbonyl compounds with enecarbamates have been developed. Stable and storable enecarbamates work as surrogates of aliphatic aldehyde-derived imines, which are known to be difficult to isolate and store.