The first side-on bound metal complex of diazene, HN=NH

The first side-on bound metal complex of diazene, HN=NH
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DOI:
10.1039/b802039f
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发表时间:
2008-01-01
影响因子:
4.9
通讯作者:
Turner, Peter
Turner, Peter
中科院分区:
化学2区
文献类型:
--
作者:
Field, Leslie D.;Li, Hsiu L.;Turner, Peter

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在钾石墨存在下,[Fe(dmpe)(2)Cl-2]与肼反应,合成了侧键金属配合物[Fe(NH=NH)(dmpe)(2)] 2,并用N-15 NMR谱和X-射线晶体学进行了表征。
The side-on bound metal complex of diazene cis[Fe(NH=NH)(dmpe)(2)] 2 was synthesised by reaction of [Fe(dmpe)(2)Cl-2] with hydrazine in the presence of potassium graphite and characterised by N-15 NMR spectroscopy and X-ray crystallography.