Degradation of carbon tetrachloride in the presence of iron and sulphur containing compounds.
Degradation of carbon tetrachloride in the presence of iron and sulphur containing compounds.
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DOI：
10.1016/0045-6535(94)90279-8
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发表时间：
1994-10
期刊：
影响因子：
8.8
通讯作者：
E. Lipczynska‐kochany;S. Harms;R. Milburn;G. Sprah;N. Nadarajah
中科院分区：
文献类型：
--
作者：
E. Lipczynska‐kochany;S. Harms;R. Milburn;G. Sprah;N. Nadarajah
在有氧条件下，研究了几种硫化合物：硫酸钠、硫化钠、硫化亚铁、黄铁矿和有机磺酸对铁 (FeO) 诱导的四氯化碳降解动力学的影响。据观察，所有研究的硫化合物都显着加速了反应。讨论了所研究过程的机理以及它们对原位和地上处理中铁诱导污染物脱卤效率的可能影响。
The effect of several sulphur compounds: sodium sulphate, sodium sulphide, ferrous sulphide, pyrite and an organosulphonic acid on the kinetics of the iron (Fe0) induced degradation of carbon tetrachloride was examined under aerobic conditions. It was observed that all of the sulphur compounds investigated significantly accelerated the reaction. The mechanisms of the processes studied as well as their possible influence on the efficiency of the iron-induced dehalogenation of pollutants, bothin situand in above-ground treatment are discussed.