Bio-inspired synthesis of polymer–inorganic nanocomposite materials in mild aqueous systems
Bio-inspired synthesis of polymer–inorganic nanocomposite materials in mild aqueous systems
复制标题
温和水体系中聚合物-无机纳米复合材料的仿生合成
DOI：
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发表时间：
2013
期刊：
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通讯作者：
Ayae Sugawara
中科院分区：
文献类型：
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作者：
Ayae Sugawara
生物矿化是生物创造各种复杂复合材料的过程，如骨骼和贝壳，是以环境友好的方式制造材料的理想模式。本文综述了生物矿化合成聚合物-无机复合材料的最新进展，包括(1)不溶性聚合物、可溶酸性聚合物和无机离子相互作用合成的聚合物-碳酸钙薄膜；(2)在水凝胶纳米颗粒支架上合成的聚合物纳米凝胶-磷酸钙纳米颗粒；(3)胶体二氧化硅纳米颗粒通过与嵌段共聚物相互作用自组装成各向异性结构。
Biomineralization, the process by which organisms create a variety of sophisticated composites such as bone and shell, is an ideal model toward materials fabrication in an environmentally friendly way. This article reviews recent progress in the biomineralization-inspired synthesis of polymer–inorganic composites including (1) polymer–calcium carbonate thin films synthesized by interaction among insoluble polymer, soluble acidic polymer, and inorganic ions; (2) polymer nanogel–calcium phosphate nanoparticles synthesized on scaffolds of hydrogel nanoparticles; and (3) colloidal silica nanoparticles made to self-assemble into anisotropic structures by interaction with block copolymers.