An abrupt spin crossover FeII complex based on homochiral chain

An abrupt spin crossover FeII complex based on homochiral chain
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基于纯手性链的突变自旋交叉 FeII 配合物

DOI:
10.1246/cl.2005.1092
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发表时间:
2005
期刊:
影响因子:
1.6
通讯作者:
N. Matsumoto
N. Matsumoto
中科院分区:
化学4区
文献类型:
--
作者:
N. Bréfuel;S. Shova;J. Tuchagues;N. Matsumoto

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合成了一种新的Fe I I配合物[FeHL 2 -Me]ClO 4,其中H2 L2-Me表示[双(2-甲基-4-甲酰基咪唑烷)氨丙基]乙二胺.该配合物在T1/ 2 = 165.5K时发生了自旋交叉,并通过相邻分子的咪唑基和咪唑基之间的氢键形成了同手性ID链结构.
A new Fe I I complex with a linear hexadentate ligand involving one terminal imidazole and one terminal imidazolato moiety, [FeHL 2 - M e ]ClO 4 , has been synthesized, where H 2 L 2 - M e denotes [bis(2-methyl-4-formylimidazolidene)aminopropyl]ethylenediamine. This complex shows an abrupt spin-crossover at T 1 / 2 = 165.5 K and assumes a homochiral ID chain structure through hydrogen bonds between the imidazole and imidazolato groups of adjacent molecules.
DOI: 10.1021/ic034495f
发表时间: 2003-11
影响因子: 4.6
作者:
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自旋交叉树枝状聚合物:热自旋跃迁的代数依赖性协同性
DOI: --
发表时间: 2005
期刊: Journal of American Chemical Society (印刷中)
影响因子: --
作者:
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通讯作者: T.Aida