Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex.
Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex.
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DOI：
10.1039/b801171k
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发表时间：
2008-05
影响因子：
4.9
通讯作者：
Bao Li;J. Tao;Haoling Sun;O. Sato;Rong-Bin Huang;Lan-Sun Zheng
中科院分区：
文献类型：
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作者：
Bao Li;J. Tao;Haoling Sun;O. Sato;Rong-Bin Huang;Lan-Sun Zheng
制备了一种钴配合物[[Co(dpqa)]2(dhbq)](PF6)3 (（PF6)3, dhbq =去质子化2,5-二羟基-1,4-苯醌，dpqa = di（2-吡啶基甲基）- n-（喹啉-2-基甲基）胺），并通过x射线衍射、电化学、ESR、热、光诱导磁测量对其进行了研究；结果表明，辅助配体精细调节了影响VT行为的结构因素和分子间相互作用。
A cobalt complex [[Co(dpqa)]2(dhbq)](PF6)3 ((PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.