(Tetrakis(2-pyridylmethyl)ethylenediamine)iron(II) perchlorate, the first rapidly interconverting ferrous spin-crossover complex

(Tetrakis(2-pyridylmethyl)ethylenediamine)iron(II) perchlorate, the first rapidly interconverting ferrous spin-crossover complex
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(四(2-吡啶基甲基)乙二胺)高氯酸铁(II),第一个快速互变的亚铁自旋交叉络合物

DOI:
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发表时间:
1990
期刊:
影响因子:
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通讯作者:
D. Hendrickson
D. Hendrickson
中科院分区:
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文献类型:
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作者:
H. Chang;J. McCusker;H. Toftlund;S. Wilson;A. Trautwein;H. Winkler;D. Hendrickson

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本文报道了第一个以高于57 Fe穆斯堡尔时间尺度的速率在高自旋态和低自旋态之间转换的Fe II自旋交叉配合物的制备和表征。[Fe(tpen)](clo4)2/ 3h2o在单斜空间群C2/c中结晶。
The preparation and characterization of the first Fe II spin-crossover complex that interconverts between high- and low-spin states at a rate faster than the 57 Fe Mossbauer time scale is reported. [Fe(tpen)](ClO 4 ) 2 .2/3H 2 O crystallizes in the monoclinic space group C2/c.