Synthetic Study on Acremoxanthone A, Part 2: Model Study on the EFG Xanthone Moiety through a Nitrile Oxide Cycloaddition?SNAr Sequence
Synthetic Study on Acremoxanthone A, Part 2: Model Study on the EFG Xanthone Moiety through a Nitrile Oxide Cycloaddition?SNAr Sequence
复制标题
Acremoxanthone A 的合成研究，第 2 部分：通过氧化腈环加成的 EFG 呫吨酮部分的模型研究？SNAr 序列
DOI：
10.1055/a-1303-5613
复制
发表时间：
2020
期刊：
影响因子：
2
通讯作者：
Takikawa Hiroshi
中科院分区：
文献类型：
--
作者：
Suzuki Keisuke;Nakakohara Hiroshi;Hirano Yoichi;Ohmori Ken;Takikawa Hiroshi
为了全合成acremoxanthone A，我们报道了EFG环系统构建的模型研究。其关键步骤包括：（1）氧化芳腈与二烯酮的分子间1，3-偶极环加成反应;（2）SNAr反应构建F环。
Toward a total synthesis of acremoxanthone A, we report a model study on the construction of the EFG ring system. The key steps include (1) an intermolecular 1,3-dipolar cycloaddition of an aryl nitrile oxide with a dienone, and (2) an SNAr reaction for construction of the F ring.