Mechanistic guidelines in nonreductive conversion of CO2: the case of cyclic carbonates
Mechanistic guidelines in nonreductive conversion of CO2: the case of cyclic carbonates
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DOI：
10.1039/d0cy00544d
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发表时间：
2020-06-07
影响因子：
5
通讯作者：
Kleij, Arjan W.
中科院分区：
文献类型：
--
作者：
Della Monica, Francesco;Kleij, Arjan W.
二氧化碳的非还原转化在均相催化领域受到了广泛的关注，特别是在环状有机碳酸酯生成过程中。虽然这类碳酸盐的合成在大多数科学贡献中处于中心地位，对催化剂设计起着至关重要的作用，但对允许发生更具挑战性的转化的机械必要条件的关注要少得多。在这篇观点文章中，主要考虑到实验和理论上的突破性结果，详细总结了导致更好地理解为环状有机碳酸酯提供有效制备路线的流形的努力。
Nonreductive conversion of carbon dioxide has received wide attention in the area of homogeneous catalysis, especially in the context of cyclic organic carbonate formation processes. Whereas the synthesis of such carbonates has been central in the majority of the scientific contributions with a crucial role for catalyst design, much less attention has been paid to the mechanistic requisites that allow for more challenging transformations to occur. In this perspective article, a detailed summary of the efforts leading to a better understanding of the manifolds providing efficient preparative routes for cyclic organic carbonates is presented, considering primarily experimental and theoretical breakthrough results.