The production of O(1S) from dissociative recombination of O2 +
The production of O(1S) from dissociative recombination of O2 +
复制标题
O2 解离重组产生 O(1S)
作者：
S. Guberman
对电子温度在100~3000K范围内O2(+)的解离结合生成O(1D)的速率进行了大规模从头算计算，结果表明，从v=0到3000K，1-β-u态是主要的解离途径，3-sigma-u(-)态是从v=1和v=2最重要的解离途径。在室温附近，由v=0产生O(1d)的总速率为2.21(+0.21，-0.24)×10(-7)x(Tsube/300)exp-0.46。在300K时，v=1和v=2比v=0分别小约17%和47%。
The results of large scale ab initio calculations of the rates for production of O(1D) by dissociative combination of O2(+) are presented for electron temperatures in the range 100 to 3000 K. A 1-delta-u state is the dominant dissociative route from v = 0 and a 3-sigma-u(-) state is the most important route from v = 1 and v = 2. The calculated total rate for O(1D) production from v = 0 is 2.21(+0.21,-0.24) x 10(-7) x (T sub e/300) exp -.46 near room temperature. The v = 1 and v = 2 rates are about 17% and 47% smaller respectively, than the v = 0 rate at 300 K.