Nanocatalytic Spontaneous Ignition and Self-Supporting Room-Temperature Combustion

Nanocatalytic Spontaneous Ignition and Self-Supporting Room-Temperature Combustion
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DOI:
10.1021/ef0496754
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发表时间:
2005-04
期刊:
影响因子:
5.3
通讯作者:
Zhiyu Hu;V. Boiadjiev;T. Thundat
Zhiyu Hu;V. Boiadjiev;T. Thundat
中科院分区:
工程技术3区
文献类型:
--
作者:
Zhiyu Hu;V. Boiadjiev;T. Thundat

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Stable and reproducible spontaneous self-ignition and self-supporting combustion have been achieved at room temperature by exposing nanometer-sized catalytic particles to methanol/air or ethanol/air gas mixtures. Without any external ignition, structurally supported platinum nanoparticles instantaneously react with the gas mixtures. The reaction releases heat and produces CO2 and water. Such reactions starting at ambient temperature have reached both high (>600 °C) and low (a few tenths of a degree above room temperature) reaction temperatures. The reaction is controlled by varying the fuel/air mixture. Catalytic activity could be dramatically changed by reducing particle size and changing particle morphology.