How to overcome Coulomb explosions in labile dications by using the [B(12)Cl(12)](2-) dianion.
How to overcome Coulomb explosions in labile dications by using the [B(12)Cl(12)](2-) dianion.
复制标题
如何使用 [B(12)Cl(12)](2-) 二价阴离子克服不稳定双阳离子中的库仑爆炸。
DOI:
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发表时间:
2009
影响因子:
4.9
通讯作者:
Christopher Schulz
中科院分区:
文献类型:
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作者:
C. Knapp;Christopher Schulz
The dicationic homoleptic lithium-sulfur dioxide complex [Li(2)(SO(2))(8)](2+) in [Li(2)(SO(2))(8)][B(12)Cl(12)] has been characterized by X-ray diffraction; [Li(2)(SO(2))(8)](2+) is stabilized in the solid state by the weakly-coordinating dianion [B(12)Cl(12)](2-) and the high lattice enthalpy of the resulting dication-dianion salt.