How to overcome Coulomb explosions in labile dications by using the [B(12)Cl(12)](2-) dianion.

How to overcome Coulomb explosions in labile dications by using the [B(12)Cl(12)](2-) dianion.
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如何使用 [B(12)Cl(12)](2-) 二价阴离子克服不稳定双阳离子中的库仑爆炸。

DOI:
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发表时间:
2009
影响因子:
4.9
通讯作者:
Christopher Schulz
Christopher Schulz
中科院分区:
化学2区
文献类型:
--
作者:
C. Knapp;Christopher Schulz

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用X射线衍射法对[Li(2)(SO(2))(8)][B(12)Cl(12)]中的双阳离子均配型锂-二氧化硫配合物[Li(2)(SO(2))(8)](2+)进行了表征;[Li(2)(SO(2))(8)](2+)在固态时被弱配位的二价阴离子[B(12)Cl(12)](2-)稳定以及所得双阳离子-二价阴离子盐的高晶格焓。
The dicationic homoleptic lithium-sulfur dioxide complex [Li(2)(SO(2))(8)](2+) in [Li(2)(SO(2))(8)][B(12)Cl(12)] has been characterized by X-ray diffraction; [Li(2)(SO(2))(8)](2+) is stabilized in the solid state by the weakly-coordinating dianion [B(12)Cl(12)](2-) and the high lattice enthalpy of the resulting dication-dianion salt.