Synthesis and structure of the first molecular thulium(II) complex: [TmI2(MeOCH(2)CH(2)OMe)(3)]
Synthesis and structure of the first molecular thulium(II) complex: [TmI2(MeOCH(2)CH(2)OMe)(3)]
复制标题
DOI：
10.1002/anie.199701331
复制
发表时间：
1997-02-03
期刊：
影响因子：
--
通讯作者：
Evans, WJ
中科院分区：
文献类型：
--
作者：
Bochkarev, MN;Fedushkin, IL;Evans, WJ
二价4f元素化学现在可以从Eu，Yb和Sm扩展到包括Tm，因为已经找到了第一个结晶学表征的分子络合物Tm II的合成路线。Tmi3与Tm在二甲氧基乙烷中反应，得到了浓绿色标题络合物。光敏复合体具有右侧所示的五角形-双锥体结构。
Divalent 4f element chemistry can now be expanded from Eu, Yb, and Sm to include Tm since a synthetic route to the first crystallographically characterizable molecular complex to Tm II has been found. The intense green title complex was isolated from the reaction of TmI 3 and Tm in dimethoxyethane. The photosensitive complex has the pentagonal‐bipyramidal structure shown on the right.