The Reaction of Carbon Disulfide with Organotin Oxides and Related Substances
The Reaction of Carbon Disulfide with Organotin Oxides and Related Substances
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二硫化碳与有机锡氧化物及有关物质的反应
DOI：
10.1021/ic50003a039
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发表时间：
1962
期刊：
影响因子：
--
通讯作者：
W. T. Reichle
中科院分区：
文献类型：
--
作者：
W. T. Reichle
当双-（三苯基锡）氧化物与二硫化碳或氧硫化碳一起加热时，氧被硫定量取代，产生纯的双-（三苯基锡）硫化物和氧硫化碳和/或二氧化碳。具有金属-氧-金属或金属-氢氧化物键的类似的锡、铅、汞和砷金属有机化合物也会与二硫化碳发生这种反应，产生硫化物。类似的磷、锗、硅和硼化合物在与二硫化碳一起加热时不会将氧交换为硫。
When bis-(triphenyltin) oxide is heated with carbon disulfide or carbon oxysulfide, the oxygen is quantitatively replaced by sulfur, yielding pure bis-(triphenyltin) sulfideand carbon oxysulfideand/or carbon dioxide. Similar tin, lead, mercury, and arsenic metalorganic compounds havingmetal-oxygen-metal or metal-hydroxide bonds also undergo this reaction with carbon disulfide to yield sulfides. Analogous phosphorus, germanium, silicon, and boron compounds do not exchange oxygen for sulfur when heated with carbon disulfide.