Addition-type Oxidation of Silylalkene Using Ozone: An Efficient Approach for Acyloin and Its Derivatives
Addition-type Oxidation of Silylalkene Using Ozone: An Efficient Approach for Acyloin and Its Derivatives
复制标题
臭氧加成型氧化硅烯：制备偶姻及其衍生物的有效方法
DOI：
10.1246/cl.2011.233
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发表时间：
2011
影响因子：
1.6
通讯作者：
K. Tomooka
中科院分区：
文献类型：
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作者：
Kazunobu Igawa;Yuuya Kawasaki;K. Tomooka
偶姻由炔烃通过氢化硅烷化，然后是加成型臭氧氧化和氢化，通过三个步骤有效地合成。关键中间体α-甲硅烷基过氧酮...
Acyloins are efficiently synthesized in three steps from alkynes via hydrosilylation followed by an addition-type ozone oxidation and hydrogenation. The key intermediate α-silylperoxy ketone is con...