Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels
Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels
复制标题
配位纳米通道中不对称硅桥[1]二茂铁的热开环聚合
DOI：
10.1039/c7cc03391e
复制
发表时间：
2017
影响因子：
4.9
通讯作者：
T.
中科院分区：
文献类型：
--
作者：
Kobayashi;Y.; Honjo;K.; Kitagawa;S.; Gwyther;J.; Manners;I.; Uemura;T.
不对称取代的[1]二茂铁的热开环聚合在一维多孔配位聚合物（PCP）纳米通道中进行。与传统的本体热聚合相反，环状聚合物的形成在通道中受到抑制。此外，所得聚合物的立构规整度取决于PCP的孔径。
Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.