Reactions Involving Like-Charged Ions. II. The Rate of Disproportionation of Uranium(V) in Deuterium Oxide1
Reactions Involving Like-Charged Ions. II. The Rate of Disproportionation of Uranium(V) in Deuterium Oxide1
复制标题
涉及同电荷离子的反应。
DOI：
10.1021/ja01149a516
复制
发表时间：
1951
影响因子：
15
通讯作者：
Richard C. Pinkerton
中科院分区：
文献类型：
--
作者：
F. Duke;Richard C. Pinkerton
本文报道的结果比克恩和奥尔曼的结果高一些。2b所涉及的最大误差来源是在确定oh++ od+时，由于甘汞电池和溶液之间的液体交界电位不确定。然而，如果我们可以假设对于重水溶液存在与普通溶液相同的液体接界，则所涉及的误差将在两个速率的比率ku/kn中抵消。
reported here are some-what higher than those obtained by Kern and Orleman. 2b The greatest source of error involved is in the determination of oh++ od+, due to an uncertain liquid junction potential between the calomel cell and solution. However, if we may assume that the same liquid junction exists for the heavy water solution as the ordinary, the error involved will cancel out in the ratio of the two rates ku/kn-