COORDINATION STABILIZED COPPER(I) FLUORIDE - CRYSTAL AND MOLECULAR-STRUCTURE OF FLUOROTRIS(TRIPHENYLPHOSPHINE)COPPER(I).ETHANOL (1-2), CU(PPH3)3F.2ETOH

COORDINATION STABILIZED COPPER(I) FLUORIDE - CRYSTAL AND MOLECULAR-STRUCTURE OF FLUOROTRIS(TRIPHENYLPHOSPHINE)COPPER(I).ETHANOL (1-2), CU(PPH3)3F.2ETOH
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DOI：
10.1016/s0020-1693(00)88590-4
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发表时间：
1981-01-01
期刊：
INORGANICA CHIMICA ACTA-ARTICLES
影响因子：
--
通讯作者：
WEBSTER, M
WEBSTER, M
中科院分区：
其他
文献类型：
--
作者：
GULLIVER, DJ;LEVASON, W;WEBSTER, M

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标题化合物的结构经单晶X-射线衍射测定。晶体结构为正交晶系，晶胞参数为13.435（2），B= 18.812（3），c= 18.739（2）nm，Z= 4，空间群为Pc 21 n（No 33）。总共测量了3291个观察到的反射，并精确到R = 0.087。铜处于畸变四面体环境（P_3F）中，Cu_（3F）= 2.325（3）、2.310（3）和2.316（2），Cu_（3F）= 2.062（6）π。用~ 1H、~（19）F和~（31）P核磁共振谱和电导率测量研究了该配合物的溶剂和温度依赖性溶液行为。简要介绍了该非溶剂化配合物的合成和性质。
The structure of the title compound has been determined by single crystal X-ray diffraction. The crystals are orthorhombica= 13.435 (2),b= 18.812(3),c= 18.739(2)Å,Z= 4, space group Pc21n(No 33). A total of 3291 observed reflections were measured and refined toR= 0.087. The copper is inn a distorted tetrahedral environment (P3F) with CuP = 2.325(3), 2.310(3) and 2.316(2), and CuF = 2.062(6)Å. The solvent and temperature dependent solution behaviour of this complex has been examined by a combination of1H,19F and31P NMR spectroscopy and conductivity measurements. The synthesis and properties of the unsolvated complex are briefly described.