Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles
Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles
复制标题
使用负载型金纳米粒子催化的甲酸铵对芳香族硝基化合物进行高度化学和区域选择性转移还原
DOI：
10.1002/adsc.201000621
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发表时间：
2011-02-11
影响因子：
5.4
通讯作者：
Fan, Kang-Nian
中科院分区：
文献类型：
--
作者：
Lou, Xia-Bing;He, Lin;Fan, Kang-Nian
A highly chemo- and regioselective reduction of a wide diversity of aromatic nitro compounds to the corresponding amines has been achieved by a combination of gold nanoparticles supported on titania and ammonium formate (HCOONH(4)) in ethanol at room temperature. Furthermore, a direct and mild route to formanilides from aromatic nitro compounds bearing different functional groups by reductive N-formylation using the gold-mediated transfer reduction protocol is also established.
