Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates
Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates
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DOI：
10.1039/b614015g
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Itoh, Toshiyuki
中科院分区：
文献类型：
--
作者：
Kawatsura, Motoi;Ata, Fumio;Itoh, Toshiyuki
在Ru-3(CO)(12)与2-(二苯基膦)苯甲酸催化的单取代丙二酸烯丙基乙酸酯与丙二酸的烷基化反应中，Ru-3(CO)(12)具有较高的区域选择性，得到了线性烷基化产物。
The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru-3(CO)(12) with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained.