The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes
The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes
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DOI：
10.1016/j.electacta.2011.06.072
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发表时间：
2011-09
影响因子：
6.6
通讯作者：
D. Plana;P. Rodríguez;M. Koper;R. Dryfe
中科院分区：
文献类型：
--
作者：
D. Plana;P. Rodríguez;M. Koper;R. Dryfe
Dimethylamine borane (DMAB) electro-oxidation in alkaline media was studied using static and rotating gold single-crystal electrodes in the hanging-meniscus configuration. DMAB oxidation showed a strong sensitivity towards surface structure on gold electrodes. In situ Fourier transform infrared (FTIR) spectroscopy revealed that the potential-dependent cleavage of the B–N bond is one of the initial steps of the oxidation process. FTIR also showed that dimethylamine is oxidised in the potential range of gold oxide formation.
