Hume-Rothery phase-inspired metal-rich molecules: cluster expansion of [Ni(ZnMe)₆(ZnCp*)₂] by face capping with Ni⁰(η⁶-toluene) and Ni(I)(η⁵-Cp*).
Hume-Rothery phase-inspired metal-rich molecules: cluster expansion of [Ni(ZnMe)₆(ZnCp*)₂] by face capping with Ni⁰(η⁶-toluene) and Ni(I)(η⁵-Cp*).
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休谟-罗瑟里相启发的富金属分子：通过用 Niâ°(δâ¶-甲苯) 和 Ni(I )(δâµ- 进行面封端，实现 [Ni(ZnMe)â(ZnCp*)â] 的簇扩展CP*)
DOI：
10.1021/ic5014335
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发表时间：
2014
影响因子：
4.6
通讯作者：
Fischer
中科院分区：
文献类型：
--
作者：
Jerabek;Trombach;Frenking;Fischer
The novel all-hydrocarbon ligand-stabilized binuclear clusters of metal–core composition Ni2Zn7E, [(η5-Cp*)Ni2(ZnMe)6(ZnCp*)(ECp*)] (1-Zn, E = Zn;1-Ga, E = Ga) and [(η6-toluene)Ni2(ZnCp*)2(ZnMe)6] (2; Cp* = pentamethylcyclopentadienyl), were obtained via Ga/Zn and Al/Zn exchange reactions using the starting compounds [Ni2(ECp*)3(η2-C2H4)2] (E = Al/Ga) and an excess of ZnMe2(Me = CH3). Compounds1-Znand1-Gaare very closely related and differ only by one Zn or Ga atom in the group 12/13 metal shell (Zn/Ga) around the two Ni centers. Accordingly,1-Znis EPR-active and1-Gais EPR-silent. The compounds were derived as a crystalline product mixture. All new compounds were characterized by1H and13C NMR and electron paramagnetic resonance (EPR) spectroscopy, mass spectrometric analysis using liquid-injection field desorption ionization, and elemental analysis, and their molecular structures were determined by single-crystal X-ray diffraction studies. In addition, the electronic structure has been investigated by DFT and QTAIM calculations, which suggest that there is a Ni1–Ni2 binding interaction. Similar to Zn-rich intermetallic phases of the Hume–Rothery type, the transition metals (here Ni) are distributed in a matrix of Zn atoms to yield highly Zn-coordinated environments. The organic residues, ancillary ligands (Me, Cp*, and toluene), can be viewed as the “protecting” shell of the 10-metal-atom core structures. The soft and flexible binding properties of Cp* and transferability of Me substituents between groups 12 and 13 are essential for the success of this precedence-less type of cluster formation reaction.
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影响因子：
4
作者：
Bollermann, Timo;Puls, Arik;Fischer, Roland A.
通讯作者：
Fischer, Roland A.
不寻常团簇 [Ni2(GaAr′)2(η1:η1-μ2-C2H4)] 的合成和表征：在 25 °C 和 1 个大气压下乙烯与 Ni(COD)(GaAr′)2 的加成反应
DOI：
--
发表时间：
2011
期刊：
影响因子：
--
作者：
Oracio Serrano;Elke Hoppe;J. Fettinger;P. Power
通讯作者：
P. Power
Ethin am [(η1-tBu2PCH2PtBu2)Ni0]-复合物片段在 η6-苯镍(0)-复合物教育中的环三聚体
DOI：
--
发表时间：
1994
期刊：
影响因子：
--
作者：
Thomas Nickel;Richard Goddard;C. Krüger;K. Pörschke
通讯作者：
K. Pörschke
类叶立德亚硅基配体对 Ni0(eta6-芳烃) 配合物的显着稳定作用。
影响因子：
--
作者：
A. Meltzer;C. Präsang;Carsten Milsmann;M. Driess
通讯作者：
M. Driess
DOI：
--
发表时间：
1996
期刊：
影响因子：
--
作者：
J. G. Snijders;A. J. Sadlej
通讯作者：
A. J. Sadlej