Sb2Se3-Sensitized Inorganic-Organic Heterojunction Solar Cells Fabricated Using a Single-Source Precursor

Sb2Se3-Sensitized Inorganic-Organic Heterojunction Solar Cells Fabricated Using a Single-Source Precursor
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DOI:
10.1002/anie.201308331
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发表时间:
2014-01-27
影响因子:
16.6
通讯作者:
Seok, Sang Il
Seok, Sang Il
中科院分区:
化学1区
文献类型:
--
作者:
Choi, Yong Chan;Mandal, Tarak Nath;Seok, Sang Il

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报道了Sb_2Se_3敏化异质结太阳能电池的光伏性能,该电池是通过在介孔二氧化钛上简单地沉积Sb_2Se_3,采用单源前驱体溶液多次旋涂和热分解的方法制备的。采用Poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b‘]dithiophene)-alt-4,7(2,1,3-benzothioadiazole)]作为空穴传输材料。最高效率电池的短路电流密度为22.3 mA cm(-2),开路电压为304.5 mV,填充系数为47.2%,在标准测试条件下(辐照1000Wm(-2),空气质量=1.5G),功率转换效率为3.21%。这项研究的结果表明,所开发的方法具有很高的潜力,可以作为一种简单而有效的方法来制造高效、廉价的太阳能电池。
The photovoltaic performance of Sb2Se3-sensitized heterojunction solar cells, which were fabricated by a simple deposition of Sb2Se3 on mesoporous TiO2 by an approach that features multiple cycles of spin coating with a single-source precursor solution and thermal decomposition, is reported. Poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene)-alt-4,7(2,1,3-benzothioadiazole)] was used as the hole-transporting material. The most efficient cell exhibited a short-circuit current density of 22.3 mA cm(-2), an open-circuit voltage of 304.5 mV, and a fill factor of 47.2%, yielding a power conversion efficiency of 3.21% under standard test conditions (irradiation of 1000 Wm(-2), air mass = 1.5 G). The results of this study imply that the developed approach has a high potential as a simple and effective route for the fabrication of efficient and inexpensive solar cells.