Gold-Catalyzed Electrophilic Addition to Arylalkynes. A Facile Method for the Regioselective Synthesis of Substituted Naphthalenes
Gold-Catalyzed Electrophilic Addition to Arylalkynes. A Facile Method for the Regioselective Synthesis of Substituted Naphthalenes
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DOI：
10.1021/ol900863d
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发表时间：
2009-07-16
期刊：
影响因子：
5.2
通讯作者：
Gudla, Vanajakshi
中科院分区：
文献类型：
--
作者：
Balamurugan, Rengarajan;Gudla, Vanajakshi
提出了一种有趣的金催化芳炔亲电加成合成取代萘的方法。不同的金属六氟锑酸盐也对转化有影响。催化金的反阴离子亲和性、亲氧性和亲炔性可能在环化反应中起重要作用。
An interesting gold-catalyzed electrophilic addition to arylalkyne to synthesize substituted naphthalenes has been presented. Different metal hexafluoroantimonates have also been found to effect the transformation. Counter anion and oxo- and alkynophilicities of catalytic gold species might play an important role in this annulation reaction.