Transient and Steady-State Kinetic Studies of Formaldehyde Alkylation of Benzene to Form Diphenylmethane on HZSM-5 Catalysts

Transient and Steady-State Kinetic Studies of Formaldehyde Alkylation of Benzene to Form Diphenylmethane on HZSM-5 Catalysts
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DOI:
10.1021/acscatal.0c02991
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发表时间:
2020-08
期刊:
影响因子:
12.9
通讯作者:
Brandon Foley;A. Bhan
Brandon Foley;A. Bhan
中科院分区:
化学1区
文献类型:
--
作者:
Brandon Foley;A. Bhan

文献摘要

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对 HZSM-5 中 HCHO 和苯形成二苯甲烷 (DPM) 机理的稳态和瞬态动力学相结合的研究揭示了两个动力学相关步骤——苯的烷基化。
A combined steady-state and transient kinetic study on the mechanism of diphenylmethane (DPM) formation in HZSM-5 from HCHO and benzene revealed two kinetically relevant steps—the alkylation of ben...